1,2,3-Triazol-5-ylidene- vs. 1,2,3-triazole-based tricarbonylrhenium( i ) complexes: influence of a mesoionic carbene ligand on the electronic and biological properties

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Two series of tricarbonylrhenium( i ) complexes were thoroughly compared. One 1,2,3-triazole-based complex displayed astounding photoluminescence properties, while one triazolylidene-based complex showed promising antibacterial activity.