The novel title compound, [Re(C26H20N2)(C2H3N)(CO)3](PF6), has been synthesized and found to crystallize in the monoclinic system with space group P21/n. The molecular ionic structure consists of an ReI complex cation and a PF6− anion, where the Re atom is octahedrally coordinated by chelating dimethyldiphenylphenanthroline, three carbonyl groups and acetonitrile.
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Sun et al. (2001) studied this question.
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