Resolution of racemic water-soluble [Ru(diimine)3]Cl2 complexes 2 can be efficiently performed by asymmetric extraction with lipophilic TRISPHAT ions Δ-1. Phase separation allows the isolation of the Δ and Λ enantiomers of the cationic complexes with selectivities (d.r.) of up to 49:1 (see scheme).
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Lacour et al. (2000) studied this question.
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