Property investigation of polypropylene/multiwall carbon nanotube nanocomposites prepared via in situ polymerization

In this study, polypropylene/carbon nanotube nanocomposites were prepared via in situ polymerization using a bi‐supported Ziegler − Natta catalytic system. In this system, magnesium ethoxide and multiwall carbon nanotubes ( MWCNTs ) are jointly used as catalyst supports. SEM images reveal the distribution and quite good dispersion of MWCNTs throughout the polypropylene ( PP ) matrix. The thermal properties of the samples were examined using DSC and TGA tests. The results show that the crystallization temperature of the nanocomposites significantly increases while the melting point is not markedly affected. In addition, the thermal stability is improved. The melt rheological properties of PP / MWCNT nanocomposites in the linear and nonlinear viscoelastic response regions were studied. An increment of the complex viscosity ( η * ), storage modulus ( G ′) and loss modulus ( G ′′) and a decrement of the loss factor (tan δ ) compared with neat PP are observed. Steady shear flow experiments show an increase in shear viscosity with increasing the MWCNT content.