“Supra”Cp: Fivefold Negishi coupling of pentaiodocymantrene resulted in radial oligocyclopentadienyl metal complexes (see scheme). These complexes show fascinating conformational and chemical behavior, including MM and CpCp bond formation and the liberation of the novel supraligand penta(ferrocenyl)cyclopentadiene. dba=dibenzylideneacetone.
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Yu et al. (2006) studied this question.
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