A novel solid-phase 3D metal-organic coordination network catalyst was prepared via self-assembly from PdCl2(CH3CN)2 and a trisphosphine hub with three flexible alkyl-chain linkers. This insoluble network complex efficiently catalyzed the Suzuki-Miyaura reaction under atmospheric conditions in water. This catalyst was reused without loss of catalytic activity.
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Yamada et al. (2006) studied this question.
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