High-efficiency PMS activation by difunctional Co-Fe PBA/g-C3N4 S-scheme heterojunction for oxytetracycline degradation: Performance evaluation and mechanism insight

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The utilization of sulfate radical-based advanced oxidation processes (SR-AOPs) has captivated the academic community due to their minimal energy requirements and superior efficacy in peroxomonosulfate (PMS) activation for pollutant decomposition. Notwithstanding these advantages, engineering an effective and economical catalyst for PMS activation presents a considerable hurdle. In the present study, a metal-organic framework of Co Fe PBA is ingeniously anchored onto g-C 3 N 4 nanosheets , resulting in the formation of an innovative Co Fe PBA/g-C 3 N 4 S-scheme heterojunction that demonstrates remarkable efficiency in PMS activation. Intriguingly, the catalytic efficiency of Co Fe PBA/g-C 3 N 4 surpasses that of g-C 3 N 4 and Co Fe PBA by 7-fold and 2.33-fold, respectively. The heightened activity of Co Fe PBA/g-C 3 N 4 heterojunction is attributed to the enhanced charge transfer efficiency, a consequence of the successful heterojunction formation. Concurrently, the ability of photoexcited electrons to reduce Co 3+ /Fe 3+ to Co 2+ /Fe 2+ bolsters PMS activation. Significantly, this heterojunction retains unparalleled stability in degrading oxytetracycline without discernible performance attenuation, heralding its commendable prospects in real-world applications. Besides, mechanism exploration indicates that SO 4 − , h + , and electron transfer contribute to oxytetracycline degradation in the Co Fe PBA/g-C 3 N 4 system. This investigation serves as a beacon for the strategic development of highly active and stable catalysts for PMS activation, aiming at environmental decontamination .