The reaction of Cp2TiCl2 with LiAlH4 forms the complex Cp2Ti(AlH3)2 [1] with the evolution of H2. Treatment of [1] with 1-octene gave the isolable titanium complex which was characterized as [Cp2Ti(AlH3)2][C6H13CH=CH2] [2a]. The roles of [1] and [2a] in the catalytic hydrometalation and the catalytic isomerization of olefins are discussed.
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Isagawa et al. (1977) studied this question.
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