Control of the conformation of the fluorenylidene moiety is achieved through an intramolecular interaction between the fluorenylidene moiety and the axial ligand during the oxidative addition and successive substitution of [PtII(fm)] to give [PtIV(X)(X′)(fm)] (fm=9-fluorenylidenemalonate; see scheme). The conformation of the fm moiety can be effectively induced by the fluorenylidene-philicity of the axial X/X′ ligands, OOCCH3>OCH3>OH.
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Lee et al. (2001) studied this question.
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