The e.s.r. spectrum of the bent mixed valence Mn(III/II/III)(saladhp)2(OAc)4(MeOH)2[saladhp = 2-(salicylideneaminato)- 1,3-dihydroxy-2-methylpropane] in dimethylformamide provides the observation of a multiline e.s.r. signal from a trinuclear mixed-valence manganese complex and allows for the comparison of magnetic and spectroscopic properties of related models for the photosynthetic water oxidizing enzyme.
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Kessissoglou et al. (1989) studied this question.