Templated, macroporous Mg–Al hydrotalcites synthesised via alkali-free co-precipitation exhibit superior performance in the transesterification of C4–C18triglycerides for biodiesel production, with rate-enhancement increasing with alkyl chain length. Promotion reflects improved diffusion of bulky triglycerides and accessibility of active sites within the hierarchical macropore–micropore architecture.
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Woodford et al. (2012) studied this question.
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