Functional inner space: A gigantic ring-shaped {Mo154} polyoxometalate cluster anion can be stabilized by encapsulation in dimethyldioctadecylammonium (DODA) cations. Its inner nanospace enables adsorption of gases and vapors, and it acts as a water-tolerant solid acid catalyst (see scheme).
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Noro et al. (2009) studied this question.
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