Silicate layers cross-linked by interlayer VO5 square pyramids form the basis of the three-dimensional frameworks of the structures of the title compounds (the structure of K2(VO)(Si4O10)⋅H2O is depicted). Alkali metal cations (•) and water molecules (○) occupy nonframework sites in these structures, which were synthesized hydrothermally.
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Wang et al. (2001) studied this question.
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