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Palladium(II) carbene complexes with a 1,3-diallylimidazolidin-2-ylidene ligand (L Allyl ) were prepared and characterized by IR, NMR, and mass spectra. The trans → cis rearrangement of the trans -[PdCl 2 (L Allyl ) 2 ] complex was observed. The relative thermodynamic stability of these isomers was studied using DFT calculations.
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Chamizo et al. (2002) studied this question.
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