Reversible Light-Driven Structural Changes between the Mono- and Bilayer Stacking Alignments in 4-Octadecyloxystilbazolium Arylcarboxylate Films

The present investigation deals with the light-driven morphological changes in multilamella films of N-methyl-4-octadecyloxystilbazolium arylcarboxylates (C18OStz+X-) cast on glass slides. The results of XRD analysis show a photostimulated layer expansion and shrinkage of the stacked thin films along the c-axis under alternative illumination at >350 and 254 nm, respectively. It was revealed that such lamellar changes could be switched either way by a reversible transformation between the mono- and bilayer units in these stacked multilamella films. Moreover, such controlled structural adjustments in the alignment could be initiated by the photocyclodimerization of the stilbazolium moieties of the arylcarboxylate salts; i.e., a monolayer-to-bilayer transformation could be induced at a stage of only 10% cyclodimer formation. The photoinduced patterning on the surface of the films was also analyzed by SEM and fluorescence microscopic investigations.