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Abstract (+)-(R)-α(p-Tolylsulfinyl)acetophenone (I) reacts with alkyl Grignard reagents in ethyl ether to give the corresponding diastereomeric alcohols (II). The ratio of RSSC -II and RS RC-II obtained was about 7 : 3. The 1,3-asymmetric induction in this reaction is discussed.
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Kunieda et al. (1974) studied this question.
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