A series of new phosphine‐thiazole compounds has been synthesized and used as efficient ligands in the palladium‐catalyzed asymmetric intermolecular Heck coupling of 2,3‐dihydrofuran with aryl triflates and cyclohexenyl triflate. Microwave heating was used to accelerate the reactions and gave complete conversions in as little as one hour. Products were obtained with good to excellent enantioselectivities.
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Kaukoranta et al. (2007) studied this question.
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