An Unexpected Photoelectronic Effect from [Co(en)3]2(Zr2F12)(SiF6)⋅4 H2O, a Compound Containing an H‐Bonded Assembly of Discrete [Co(en)3]3+, (Zr2F12)4−, and (SiF6)2− Ions

Hydrogen-bonded network: A hydrothermal synthesis delivers the titled compound, which consists of an H-bonded network of discrete [Co(en)3]3+, (Zr2F12)4−, and (SiF6)2− ions. It exhibits an unexpected photoelectronic effect in the near-UV region (see figure).