Enantiopure 1,1′:4′,1′-ternaphthalene compounds were synthesized via enantioresolution of 1,1′:4′,1′-ternaphthalene-2,2′-dimethanol (2) by the chiral phthalic acid amide method. The CD spectra of chiral 1,1′:4′,1′-ternaphthalene compounds synthesized showed typical intense exciton split CD Cotton effects, from which the absolute stereochemistry of these 1,1′:4′,1′-ternaphthalene compounds was unambiguously determined by the CD exciton chirality method. Chirality 9:623–625, 1997.
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Harada et al. (1997) studied this question.
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