The phosphination of styrene‐bromostyrene‐divinylbenzene terpolymers as a function of their textural and chemical characteristics has been studied. A small decrease of both specific area and porous volume with phosphination was observed. Chemical analysis showed the presence of side reactions like reduction of the halogen, addition on the double bond, and crosslinking reaction involving the different functional groups. The phosphorous distribution was inhomogeneous; this was attributed to a difference of crosslinking density in the beads due to the particular morphology of this type of support.
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Bacquet et al. (1991) studied this question.
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