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September 15, 2026Precision ChemistryOpen Access

Reticularized Silver Nanoclusters: From Luminescence to Sensing

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Authors

TITsukasa IrieTohoku UniversityTKTokuhisa KawawakiTokyo University of ScienceSDSaikat Das

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Implication

Review demonstrates enhanced stability and tunable optical emission in reticularized silver nanocluster frameworks, highlighting their utility for chemical sensing and molecular diagnostics.

Key Points

  • To examine how assembling discrete silver nanoclusters into reticular metal–organic frameworks stabilizes the clusters and optimizes their photophysical properties for sensing and optical applications.
  • Review and synthesis of published literature on silver nanocluster metal–organic frameworks (Ag NCMOFs).
  • Analysis of framework design parameters, including cluster nuclearity, ligand shells, linkers, topology, and pore environments across various applications.
  • Reticularization incorporates fragile molecular silver nanoclusters into stable, periodic extended frameworks, overcoming weak processability and environmental sensitivity.
  • Lattice confinement activates advanced photophysical behaviors, including framework-rigidified emission, charge-transfer pathways, triplet-state activation, and circularly polarized luminescence.
  • Porous crystalline architectures serve as sensitive optical and Raman platforms for detecting volatile organic compounds, heavy metal ions, antibiotics, explosives, and oxygen.

Cite This Study

Irie et al. (2026) studied this question.

synapsesocial.com/papers/6aa913d99013453be30a219ehttps://doi.org/10.1021/prechem.6c00097
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