The deactivation of vibrationally excited HCl produced via excimer laser photolysis of chloroethylenes has been studied in both the gas phase and in liquid xenon solution. The rate of deactivation of HCl* by the chlorethylene parent is significantly faster in liquid xenon than in the gas phase. This occurs due to enhancement of the vibration–vibration energy transfer probability in solution. The nature of this enhancement is discussed.
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Knudtson et al. (1985) studied this question.
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