We report the formation and structure of poly(lactic acid) (PLA) nanofiber shish kebabs (NFSKs) containing stereocomplex crystal (SC) shish and SC/homocrystal (HC) kebabs. PLA-based NFSKs were obtained by combining electrospinning and controlled polymer crystallization in order to investigate the interplay between PLA SC and HC formation. Nanofibers were produced by electrospinning poly(l-lactic acid)/poly(d-lactic acid) (PLLA/PDLA) blends and were used as the shish. A secondary polymer (either PDLA or PLLA/PDLA blends) was decorated on the nanofiber by an incubation method to form kebab lamellae. We show that both SC and HC kebab crystals can be formed using a SC shish following a soft epitaxy mechanism, while the subtle morphological differences in the resultant NFSKs reveal the propensity of SC nuclei in SC/HC crystallization.
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Xie et al. (2020) studied this question.
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