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April 16, 2003Angewandte Chemie

Solid‐State Supramolecular Chirogenesis: High Optical Activity and Gradual Development of Zinc Octaethylporphyrin Aggregates

Victor Borovkov Takunori Harada Guy A. Hembury Yoshihisa Inoue Reiko Kuroda

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Abstract

Die langsame Bildung helicaler J-Aggregate erfolgt bei der Wechselwirkung von (achiralem) Zinkoctaethylporphyrin mit enantiomerenreinem 1-Cyclohexylethylamin im festen Zustand. Diese stabilen chiralen Festkörperaggregate zeigen ausgeprägte optische Aktivität, wie die Circulardichroismus-Spektren erkennen lassen (siehe Bild).

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Borovkov et al. (2003) studied this question.

synapsesocial.com/papers/6aa9209cce29879c7a0dfe9f https://doi.org/10.1002/ange.200250524

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