The first microwave‐accelerated Hiyama cross‐coupling reactions are reported. The reactions of aryl bromides and activated aryl chlorides with PhSi(OMe)3 [or C2H3Si(OMe)3] are complete within minutes using a modified catalyst system that can be prepared from commercially available reagents in situ. The microwave‐accelerated reactions proceed under relatively mild conditions (110–115 °C)
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Matthew L. Clarke (2005) studied this question.
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