Ruthenium–Olefin Complexes: Effect of Ligand Variation upon Geometry

The development of a model system to study ruthenium-olefin complexes relevant to the mechanism of olefin metathesis has been reported recently. Upon addition of the ligand precursor 1,2-divinylbenzene to [RuCl(2)(Py)(2)(H(2)IMes)(==CHPh)] (H(2)IMes=1,3-dimesityl-4,5-dihydroimidazol-2-ylidene), two ruthenium-olefin adducts are formed. Based on (1)H NMR spectroscopy experiments and X-ray crystallographic analysis, these complexes are assigned as side-bound isomers in which the olefin and H(2)IMes ligands are coordinated cis to each other. Herein is reported an investigation of the generality of these observations through variation of the N-heterocyclic carbene ligand and the ligand precursor.