Fabrication of Complex Architectures Using Electrodeposition into Patterned Self-Assembled Monolayers

Patterned self-assembled monolayers (SAMs) on solid surfaces can be used to direct electrodeposition to occur at specific locations. In previous work, single deposition steps have been used to create islands or lines in patterned SAMs. In this paper we present strategies for creating more complex structures, including via-like structures and multicomponent lines. We also show how finite size effects can be exploited to produce arrays of single-crystal islands.