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December 1, 1979Chemistry Letters

Synthesis of Alkyl- Or Aryl-Substituted Hetelocycles: Nickel Complex Catalyzed Coupling Reaction of Heterocyclic Sulfides and Thiols With Grignard Reagents

Hisashi Takei Morikazu Miura Hideyuki Sugimura Hisashi Okamura

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Abstract

Heterocyclic sulfides and thiols react with Grignard reagents in the presence of NiCl2(Ph2PCH2CH2CH2PPh2) to afford the cross-coupling products in high yields. The reaction of 2,2′-dipyridyl disulfide with 3-phenylpropylmagnesium bromide is also described.

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Takei et al. (1979) studied this question.

synapsesocial.com/papers/6aa93d306db186eb9162ecfb https://doi.org/10.1246/cl.1979.1447

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