An efficient procedure for synthesizing oxazines was developed by the palladium(0)‐catalyzed intramolecular cyclization of a benzamide through a π‐allylpalladium(II) complex. Unlike other palladium‐catalyzed reactions, the temperature was found to be a key factor in determining the stereochemistry of the oxazine. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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Joo et al. (2007) studied this question.
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