{112} ⟨111⟩ mechanical twinning and stress-induced omega transition were observed by high-resolution transmission electron microscope in a metastable β titanium alloy with chemical composition of Ti-23Nb-0.7Ta-2Zr-1.2O at. % after deformation. The orientation relationships between the ω phase and β parent matrix are (1¯010)ω‖(211)β, [12¯10]ω‖[01¯1]β and [0001]ω‖[1¯11]β, and the habit plane of (1¯010)ω‖(211)β for the stress-induced ω transition is different from that of (0001)ω‖(111)β often observed for the thermal ω transition. Both mechanical twinning and ω transition arise from the shear along ⟨111⟩ {112}. A dislocation mechanism for mechanical twinning and stress-induced ω transition was discussed additionally.
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