Answers are grounded in this paper and cite their sources.
Physical and structural properties of the MMX-type halogen-bridged mixed-valence complex, Pt2(dta)4I (dta = CH3CS2 −) were investigated. This complex exhibits metallic conduction above room temperature, which is the first observation in halogen-bridged 1-D transition-metal complexes. Below 300 K, the metal-semiconductor transition was observed. The mixed-valence state of this compound is discussed.
No takes yet. Share an insight, caveat, or question.
Kitagawa et al. (1996) studied this question.
Synapse has enriched 5 related papers. Consider them for comparative context: