Abstract α-Olefins are carbonylated to give corresponding alcohols under mild water gas shift reaction (WGSR) conditions using Rh6(CO)16-N,N,N′,N′-tetramethyl-1,3-propanediamine and 4-dimethylaminopyridine catalyst systems, α,β-Unsaturated carbonyl compounds give selectively C=C reduction products.
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Kaneda et al. (1981) studied this question.
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