January 1, 1986Journal of the Chemical Society Chemical Communications

Iridium( III ) hydrides derived from an iridium( I ) substrate by oxidative addition and cyclometallation of germanium( II ) bis(trimethylsilyl)amide; X-ray structures of [{CH 2 Me 2 SiN(R)(NR 2 )Ge}HIr(µ-Cl) 2 {Ge(NR 2 )N(R)SiMe 2 CH 2 }IrH{Ge(NR 2 ) 2 }] and [lr{GeCl(NR 2 )N(R)SiMe 2 CH 2 }(CO) 2 H{Ge(NR 2 ) 2 }](R = SiMe 3 )

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Abstract

Treatment of [{Ir(η-C8H14)2(µ-Cl)}2] with Ge(NR2)2 in n-C6H14 at 20 °C (C8H14= cyclo-octene, R = SiMe3) in the absence or presence of CO leads to [{[graphic ommitted]H{Ge(NR2)2}](1) or [[graphic ommitted](CO)2H{Ge(NR2)2}](2), respectively; the Ir–Ge distances in (1) and (2) range from 2.325(3) to 2.470(3)Å.

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Cite This Study

Hawkins et al. (1986) studied this question.

synapsesocial.com/papers/6aa95464a9624f76b4cdd6b7 https://doi.org/10.1039/c39860001689

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