Herein we report the synthesis and spectroscopic observation of a Pt complex featuring a P 2 Si═ ligand containing a central silylene donor connected to phosphines via two o -arylene linkers. Species of the type (P 2 Si═)PtR undergo a net 1,2-migration of R from Pt to Si, which leads to highly unsaturated Pt cations displaying only a very distant interaction with the weakly coordinating carborane anion.
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DeMott et al. (2015) studied this question.
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