The room-temperature reactions of stannocene, Cp*(2)Sn, with a range of primary phosphines, RPH(2), result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*(2)SnCl(2), however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.
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Naseri et al. (2010) studied this question.
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