Experimental study demonstrates high photocatalytic hydrogen evolution in a nickel polyoxometalate complex, highlighting a robust design for solar fuel generation.
A unique polyoxometalate complex made up of a tetradecanuclear nickel bisphosphonate cluster capping a {SiW9} unit has been characterized. This stable compound exhibits a high hydrogen evolution reaction photocatalytic activity under visible light irradiation via a reductive quenching mechanism.
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Paille et al. (2019) studied this question.
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