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Hydrogen (H2) can be added across a transition metal-borane bond via a 'hydride shuttle' process, enabling the recharging of borane functional groups to borohydride. Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

October 12, 2010Chemical Communications

Double addition of H 2 to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres

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Abstract

The addition of H(2) across a transition metal-borane bond is reported for the first time providing a mechanism for recharging borane functional groups to borohydride.

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Tsoureas et al. (2010) studied this question.

synapsesocial.com/papers/6aa95d65d7d677827e256f69 https://doi.org/10.1039/c0cc02245d

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Abstract

The addition of H(2) across a transition metal-borane bond is reported for the first time providing a mechanism for recharging borane functional groups to borohydride.

Double addition of H 2 to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres

Abstract

Discussion

Cite This Study

Double addition of H 2 to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres

Abstract

Discussion

Cite This Study

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