Stable group 13 metal chlorobenzene complexes of general type [( i Pr 2 -ATI)MR][B(C 6 F 5 ) 4 ](ClPh) (M = Al, Ga, In; i Pr 2 -ATI = N, N ‘ -diisopropylaminotroponiminate) have been isolated. X-ray crystallographic studies show that the PhCl ligands in these compounds are coordinated by dative M−ClPh bonding and suggest that π-stacking interactions between the PhCl phenyl ring and the i Pr 2 -ATI ligand may also contribute to the PhCl coordination.
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Korolev et al. (2001) studied this question.
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