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Single crystals and powders of Cd ( 1 − x ) Zn x S were grown using chemical transport with iodine. These components form a continuous series of solutions over the entire range of x, 0 to 1. The wurtzite structure was produced over the entire range. The lattice parameters and the composition of the solid solutions were determined to approximately 1% using x‐ray diffractometry techniques. The results provide a definitive calibration of lattice constants for the wurtzite structure of solid solutions of CdS and ZnS and allow the analysis of Cd ( 1 − x ) Zn x S samples. The variation of lattice parameters with composition was found to obey Vegard's law. The variation of the c/a ratio with composition was also linear. The ideal ratio, assuming close packing of hard spheres, occurred at 70% ZnS . The volume relationship with composition showed a slightly negative deviation from linearity. A least squares method for refining lattice parameters is described.
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Cherin et al. (1970) studied this question.
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