Zirconocene/methylaluminoxane catalysts made-to-measure (with zirconocenes such as 1) facilitate statistical incorporation of bulky cycloolefins such as dimethanooctahydronapthalene into a polyethylene chain. The new cycloolefin copolymers are extremely thermally stable and show very promising properties for optoelectronic and technical applications.
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Kaminsky et al. (1995) studied this question.
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