Cucurbit[6]-, [7]-, and [8]uril can catalyze the silver(I)-promoted desilylation of trimethylsilylalkynyl-containing pseudorotaxanes by stabilizing a key pi-alkynyl silver intermediate through favorable interactions between the metallic cation and the cavitand carbonylated portal.
No takes yet. Share an insight, caveat, or question.
Lu et al. (2010) studied this question.
Synapse has enriched 3 closely related papers on similar clinical questions. Consider them for comparative context: