Vibrational resolved constant-ionic-state spectroscopy is used to study photoionization of N2O We determine the ratio of partial photoionization cross sections for alternative vibrational levels of the N2O+ (A 2σ+) state and these vibrational branching ratios are dependent on excitation energy, implying that there is a breakdown of the Franck-Condon approximation. These results may be sampling the wings of a shape resonance.
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Poliakoff et al. (1986) studied this question.
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