A facile and rapid approximation for counting numbers of quantum states W(E,J) is described for application in the phase space theory of unimolecular bond fission reactions. The method accounts for J‐conservation. It is based on an empirical interpolation between analytical expressions of W(E,J) in the low J‐ and high J‐limits, and it is checked by extensive accurate state counting for sets of representative model molecules.
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Olzmann et al. (1992) studied this question.
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