Catalytic behavior of a bis(phenoxy-imine)Ti complex/i-Bu3Al/Ph3CB(C6F5)4 catalyst system for higher α-olefin polymerization was investigated. The catalyst system exhibited higher activities towards α-olefins having larger molecular sizes and formed ultra-high molecular weight poly(higher α-olefin)s.
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Saito et al. (2003) studied this question.
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