In-Situ Destruction of Chlorinated Hydrocarbons in Groundwater Using Catalytic Reductive Dehalogenation in a Reactive Well: Testing and Operational Experiences

A groundwater treatment technology based on catalytic reductive dehalogenation has been developed to efficiently destroy chlorinated hydrocarbons in situ using a reactive well approach. The treatment process utilizes dissolved H 2 as an electron donor, in the presence of a commercial palladium-on-alumina catalyst, to rapidly reduce common chlorinated aliphatics such as trichloroethylene and tetrachloroethylene into nonchlorinated hydrocarbons such as ethane. Rapid reaction rates permit the deployment of a treatment unit within a dual-screened well bore, allowing contaminated groundwater to be drawn from one water-bearing zone, treated within the well bore, and discharged to an adjacent zone with only one pass through the system. A demonstration groundwater treatment system based on this concept was evaluated in a chlorinated hydrocarbon contaminated aquifer at a major Superfund site. The system rapidly destroyed a variety of common contaminants such as TCE and PCE and maintained its performance for a test period of 1 year. Operation of the treatment system was optimized to maintain catalyst activity and to prevent formation of intermediate compounds.