The AIE mechanism for cationic Ir(III) complexes with triazole-pyridine ligands has been determined by the combination of an experimental and a computational study. Larger structural relaxation and weak emissive excited-state intraligand charge transfer (ILCT) characters are responsible for the non-emission in solution, whereas the non-radiative processes are efficiently restricted in the solid state, enhancing the emission.
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Wu et al. (2014) studied this question.
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