Herein, we designed and prepared a novel Fe/Fe2O3‐based catalyst, in which a remarkable synergistic effect has been revealed between Fe and Fe2O3 encapsulated in N‐doping porous carbon. The Fe‐based catalysts were fabricated via pyrolysis a mixture of MIL‐101(Fe) and melamine. The catalyst exhibits exceptionally high catalytic activity (TOFs up to 8898 h−1 which is about 100 times higher than the similar kinds of catalysts) and chemoselectivity for nitroarene reduction under mild conditions.
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Yun et al. (2018) studied this question.
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