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In the crystal, enantiomeric molecules of C 14 H 7 BrF 5 NO 2 are linked by C—H...O hydrogen bonds, forming layers parallel to the ( 1 01) plane. In addition, C—H...π interactions and Br...π contacts create layers parallel to the (10 1 ) plane. According to Hirshfeld surface analysis, the most important contributions to the crystal packing are F...H / H...F (32.4%), O...H / H...O (12.4%), F...F (11.5%), Br...F / F...Br (8.4%) and C...H / H...C (8.4%) interactions.
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Maslova et al. (2026) studied this question.
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