The gaseous MgH2 molecule has been discovered in an electrical discharge inside a high temperature furnace. The vibration–rotation emission spectrum of MgH242 was recorded with a Fourier transform spectrometer and the antisymmetric stretching mode (ν3) was detected near 1589 cm−1. In addition, three hot bands involving ν2 and ν3 were found and rotationally analyzed. The MgH2 molecule has a linear structure with an R0 Mg–H bond distance of 1.703 327(3) Å.
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Shayesteh et al. (2003) studied this question.
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