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January 1, 2005Chemical Communications

Carbon–nitrogen bond cleavage in pyridine ring systems mediated by organometallic thorium(iv) complexes

J.A. Pool Brian L. Scott Jaqueline L. Kiplinger

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Abstract

Thorium(IV) alkyl and aryl complexes of the type (C(5)Me(5))(2)ThR(2)(R = CH(2)Ph, Ph) have been found to mediate the facile ring-opening and dearomatization of the pyridine ring of pyridine N-oxide under ambient conditions to afford the first thorium eta(2)-(O,N)-oximate complexes.

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Pool et al. (2005) studied this question.

synapsesocial.com/papers/6aaba24f3780050b54fe46f3 https://doi.org/10.1039/b502439k

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